Nonlinear transmission of a tetrabrominated naphthalocyaninato indium chloride.
Identifieur interne : 002959 ( Main/Exploration ); précédent : 002958; suivant : 002960Nonlinear transmission of a tetrabrominated naphthalocyaninato indium chloride.
Auteurs : RBID : pubmed:16800543Abstract
The axially substituted complex chloro indium(III) 2-tetrabromo-3-tetra-(3,5-di-tert-butylphenyloxy)naphthalocyanine [Br4(tBu2PhO)4NcInCl (1); MW = 1996] has been synthesized for the first time, and its nonlinear transmission properties have been evaluated with the Z-scan technique in both open and closed aperture configurations at 532 nm for nanosecond pulsed radiation. The tetrabrominated complex 1 displayed a larger positive nonlinear absorption coefficient when compared to an analogous nonbrominated naphthalocyanine [(tBu2PhO)8NcInCl (2); MW = 2498]. The effect of the four Br atoms on the nonlinear optical behavior of 1 is evaluated, discussed, and compared with the nonlinear optical behavior of 2. It is shown that the bromination of the naphthalocyanine ring considerably improves the limiting properties of such a system when high-intensity radiations are produced by nanosecond laser pulses at 532 nm.
DOI: 10.1021/jp0571776
PubMed: 16800543
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Nonlinear transmission of a tetrabrominated naphthalocyaninato indium chloride.</title><author><name sortKey="Dini, Danilo" uniqKey="Dini D">Danilo Dini</name><affiliation wicri:level="3"><nlm:affiliation>Institute of Organic Chemistry, University of Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany. danilo.dini@uni-tuebingen.de</nlm:affiliation><country xml:lang="fr">Allemagne</country><wicri:regionArea>Institute of Organic Chemistry, University of Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen</wicri:regionArea><placeName><region type="land" nuts="1">Bade-Wurtemberg</region><region type="district" nuts="2">District de Tübingen</region><settlement type="city">Tübingen</settlement></placeName></affiliation></author><author><name sortKey="Calvete, Mario J F" uniqKey="Calvete M">Mario J F Calvete</name></author><author><name sortKey="Hanack, Michael" uniqKey="Hanack M">Michael Hanack</name></author><author><name sortKey="Pong, Richard G S" uniqKey="Pong R">Richard G S Pong</name></author><author><name sortKey="Flom, Steven R" uniqKey="Flom S">Steven R Flom</name></author><author><name sortKey="Shirk, James S" uniqKey="Shirk J">James S Shirk</name></author></titleStmt><publicationStmt><date when="2006">2006</date><idno type="doi">10.1021/jp0571776</idno><idno type="RBID">pubmed:16800543</idno><idno type="pmid">16800543</idno><idno type="wicri:Area/Main/Corpus">002B32</idno><idno type="wicri:Area/Main/Curation">002B32</idno><idno type="wicri:Area/Main/Exploration">002959</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The axially substituted complex chloro indium(III) 2-tetrabromo-3-tetra-(3,5-di-tert-butylphenyloxy)naphthalocyanine [Br4(tBu2PhO)4NcInCl (1); MW = 1996] has been synthesized for the first time, and its nonlinear transmission properties have been evaluated with the Z-scan technique in both open and closed aperture configurations at 532 nm for nanosecond pulsed radiation. The tetrabrominated complex 1 displayed a larger positive nonlinear absorption coefficient when compared to an analogous nonbrominated naphthalocyanine [(tBu2PhO)8NcInCl (2); MW = 2498]. The effect of the four Br atoms on the nonlinear optical behavior of 1 is evaluated, discussed, and compared with the nonlinear optical behavior of 2. It is shown that the bromination of the naphthalocyanine ring considerably improves the limiting properties of such a system when high-intensity radiations are produced by nanosecond laser pulses at 532 nm.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">16800543</PMID><DateCreated><Year>2006</Year><Month>06</Month><Day>27</Day></DateCreated><DateCompleted><Year>2007</Year><Month>07</Month><Day>23</Day></DateCompleted><Article PubModel="Print"><Journal><ISSN IssnType="Print">1520-6106</ISSN><JournalIssue CitedMedium="Print"><Volume>110</Volume><Issue>25</Issue><PubDate><Year>2006</Year><Month>Jun</Month><Day>29</Day></PubDate></JournalIssue><Title>The journal of physical chemistry. B</Title><ISOAbbreviation>J Phys Chem B</ISOAbbreviation></Journal><ArticleTitle>Nonlinear transmission of a tetrabrominated naphthalocyaninato indium chloride.</ArticleTitle><Pagination><MedlinePgn>12230-9</MedlinePgn></Pagination><Abstract><AbstractText>The axially substituted complex chloro indium(III) 2-tetrabromo-3-tetra-(3,5-di-tert-butylphenyloxy)naphthalocyanine [Br4(tBu2PhO)4NcInCl (1); MW = 1996] has been synthesized for the first time, and its nonlinear transmission properties have been evaluated with the Z-scan technique in both open and closed aperture configurations at 532 nm for nanosecond pulsed radiation. The tetrabrominated complex 1 displayed a larger positive nonlinear absorption coefficient when compared to an analogous nonbrominated naphthalocyanine [(tBu2PhO)8NcInCl (2); MW = 2498]. The effect of the four Br atoms on the nonlinear optical behavior of 1 is evaluated, discussed, and compared with the nonlinear optical behavior of 2. It is shown that the bromination of the naphthalocyanine ring considerably improves the limiting properties of such a system when high-intensity radiations are produced by nanosecond laser pulses at 532 nm.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Dini</LastName><ForeName>Danilo</ForeName><Initials>D</Initials><Affiliation>Institute of Organic Chemistry, University of Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany. danilo.dini@uni-tuebingen.de</Affiliation></Author><Author ValidYN="Y"><LastName>Calvete</LastName><ForeName>Mario J F</ForeName><Initials>MJ</Initials></Author><Author ValidYN="Y"><LastName>Hanack</LastName><ForeName>Michael</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Pong</LastName><ForeName>Richard G S</ForeName><Initials>RG</Initials></Author><Author ValidYN="Y"><LastName>Flom</LastName><ForeName>Steven R</ForeName><Initials>SR</Initials></Author><Author ValidYN="Y"><LastName>Shirk</LastName><ForeName>James S</ForeName><Initials>JS</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>J Phys Chem B</MedlineTA><NlmUniqueID>101157530</NlmUniqueID><ISSNLinking>1520-5207</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2006</Year><Month>6</Month><Day>28</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2006</Year><Month>6</Month><Day>28</Day><Hour>9</Hour><Minute>1</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2006</Year><Month>6</Month><Day>28</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1021/jp0571776</ArticleId><ArticleId IdType="pubmed">16800543</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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